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Methane Removal
Grantee Project

Tropospheric Multiphase Reactive Halogen Evolution: CAPRAM-SPARK Model Development and Application to Field Observations

Improving our ability to model reactive atmospheric halogens

Hartmut Herrmann

December 2024

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November 2026

Project Summary

Key goals of the proposed project are (i) development of an explicit multiphase halogen module considering the latest findings on Cl atom activation and cycling, (ii) performing detailed multiphase box model simulations to understand Cl atom activation, (iii) evaluation of the model developments with CVAO field data and (iv) deviation of an advanced parameterization for application in earth system models (ESMs).

The current explicit multiphase mechanism CAPRAM–HM3.0 (Hoffmann et al., 2019) will be further advanced for its detailed Cl atom activation and adjunct model simulations will result into improved Cl atom activation parameterizations for ESMs. The improved understanding of atmospheric Cl atom activation enables a better evaluation of proposed geoengineering approaches dealing with an enhanced Cl atom driven CH4 removal and its potential environmental side effects.

Team

Prof. Hartmut Herrmann is a Professor of Atmospheric Chemistry at the University of Leipzig andHead of the Atmospheric Chemistry Department (ACD) at the Leibniz Institute for TroposphericResearch (TROPOS) in Leipzig. He is a distinguished visiting Professor at the School of Environmental Science and Engineering of Shandong University at Qingdao and a Concurrent Professor in Environmental Science and Engineering at Fudan University. His research intends to understand the tropospheric multiphase system up to the level of its predictability. Model development is strongly based on experimental work both in the laboratory and in the field. Lab work utilizes state-of-the-art physical and analytical chemistry methods to study gas phase, aqueous phase, organic phase, surface and multiphase phenomena. Field work uses advanced techniques to understand chemical processing and composition of tropospheric particles, clouds and rain in the complex interplay of all the compartments involved.

Collaborators

Publications

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